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Contaminants Found During Stream Survey in Potomac River Basin

U.S. Department of the Interior
U.S. Geological Survey

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Updated: May 12, 1993

A wide variety of insecticides, semivolatile organic compounds, and trace-metal contaminants were found in streambed sediments, clams and fish in the Potomac River basin during a contaminant survey, according to scientists from the U.S. Geological Survey (USGS), Department of the Interior.

Although potentially toxic, none of the contaminants were found at concentrations that exceed any established drinking-water standards.

The survey, undertaken to document the occurrence of nearly 140 contaminants in the basin, targeted streams known or suspected to contain contaminants. It was the first major sampling activity conducted by the Potomac River basin study unit of the USGS's National Water-Quality Assessment (NAWQA) program.

"Nearly 75 percent of the contaminants that we tested for in the survey were found to be present somewhere in the basin," said James Gerhart, USGS hydrologist, Towson, Md., chief of the Potomac River basin NAWQA study unit. "Of the 139 contaminants that the samples were analyzed for, 102 were found at detectable levels, including 24 of 40 insecticides, 59 of 80 semivolatile organic compounds, and all 18 trace-metal contaminants. Possible sources of the contaminants include industrial and municipal wastewater, urban and agricultural runoff, mining activities, atmospheric deposition and the natural weathering of rocks."

"Although contaminant studies of the Potomac River basin have been conducted by federal and state agencies in the past, this is the first basinwide contaminant survey to include such a broad array of contaminants at such a wide variety of stream sites," said Gerhart. "The results will help guide us in deciding what areas and issues might be particularly critical to the assessment of water quality in the Potomac River basin."

Samples of fine-grained streambed sediment were collected in August and September 1992 from 22 sites in the Potomac River and some of its major tributaries in Washington, D.C., Virginia, Maryland, West Virginia, and Pennsylvania. In addition, samples of the Asiatic clam, Corbicula fluminea, were collected at 14 of the 22 sites, and samples of bullhead catfish were collected at 8 of the 22 sites.

Although many contaminants were found in the samples, their concentrations were generally low, and for those contaminants with established criteria, well below any criteria for human health concerns. Two streambed-sediment samples from the South Fork Shenandoah River contained mercury concentrations that exceeded Virginia's sediment criterion, however, and one sample from the South Fork Shenandoah River contained PCB's at a concentration that exceeded the U.S. Environmental Protection Agency's threshold contamination criterion. These high concentrations were not unexpected, as high concentrations of mercury and PCB's have been documented in the past at these sites by the Virginia Water Control Board. No Asiatic clam or bullhead catfish samples had concentrations of any contaminants that exceeded human health criteria. "One interesting aspect of the findings," Gerhart said, "was that although the use of the insecticides chlordane, DDT, and dieldrin has been banned in the United States for the past two decades, their detection in this survey indicates their persistence in the environment."

The bed-sediment samples were analyzed for concentrations of 40 organochlorine insecticides, 80 semivolatile organic compounds, 18 trace-metal contaminants, and PCB's. The clam and catfish tissue samples were analyzed for concentrations of 28 insecticides, 18 trace-metal contaminants, and PCB's.

Organochlorine insecticides are typically used in a wide variety of urban, suburban, forested and agricultural settings to control insect pests. Included in the insecticides that were found at one or more of the survey sites were chlordane, DDT, dieldrin, endrin, heptachlor, chlorneb, and nonachlor.

Semivolatile organic compounds and PCB's are typically associated with industrial processes and urban settings. Semivolatile organic compounds found in the survey included naphthalene, anthracene, pyrene, chrysene, phenol, cresol, acridine and phenanthridine.

Trace-metal contaminants typically result from industrial processes, mining and urban runoff, but also may originate from the weathering of natural geologic materials. Mercury, lead, arsenic, cadmium, chromium, nickel and copper were some of the trace-metal contaminants that were found in the samples.

"On the basis of the 22 sites we sampled, we can make some general statements about contaminant distribution in the Potomac River basin," said Gerhart. "For instance, sites in the Washington, D.C., metropolitan area had the highest number of insecticide detections, followed by sites in the Shenandoah Valley and the middle Potomac River area. Sites in the North Branch Potomac River area had the highest number of detections of semivolatile organic compounds and trace- metal contaminants, followed by sites in the Washington, D.C., and Shenandoah Valley areas."

The number of insecticides found at a site ranged from one at the Potomac River at Shepherdstown, W. Va., to 13 at the Anacostia River at Bladensburg, Md. The lowest number of semivolatile organic compounds (8) was found in Goose Creek near Leesburg, Va., and the highest number (33) was found at the Potomac River near Cumberland, Md., and at Bull Run near Manassas, Va. The number of trace- metal contaminants found at a site ranged from 13 to 17. PCB's were found at 20 of the 22 sites.

The sites from which samples were collected were:

The contaminant survey was conducted to investigate the presence of a wide variety of contaminants throughout the basin and to provide information that would be useful in designing selected future aspects of the study. Streams to be sampled were selected to best represent the diversity of physiographic, geologic, hydrologic, ecologic, and land-use settings present in the basin. Within these various settings, specific sampling sites were selected downstream from known contamination sources and in stream reaches where contaminants were most likely to be found.

Further information on the survey and on the specific data for each sampling site can be obtained from James Gerhart, Joel Blomquist, or Humbert Zappia (USGS, Towson, Md.) at (410) 238-4200.

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