| Table 3. Summary of pesticides detected in surface water and Groundwater in the Potomac River Basin
[MDL: Method Detection Limit; MRL: Minimum Reporting Limit; (E): concentration estimated; ug/L: micrograms per liter; <:less than] | ||||||||||
| Surface Water | Groundwater | |||||||||
| Chemical Name | MDL or MRL (µg/L) | Number of Samples Collected | Number of Sites Where Pesticide | Percent of Samples Having Detectable Concentration | 90th Percentile Concentration (µg/L) | Maximum Reported Concentration (µg/L) | Number of Sites Sampled | Number of Sites Where Pesticide Detected | 90th Percentile Concentration (µg/L) | Maximum Reported Concentration (µg/L) |
| Samples analyzed by gas chromatography with detection by mass spectrometry (Zaugg and others, 1995) (112 surface-water sites sampled for this analysis method) | ||||||||||
| Alachlor | 0.002 | 279 | 14 | 24.4a | 0.029 | 3.100 | 105 | 1a | <0.002 | 0.005 |
| Atrazine | .001 | 279 | 92 | 88.2a | .730 | 25.0 (E) | 105 | 36 | .250 | 1.20 |
| Azinphos-methyl | .001 | 275 | 4 | 3.6a | <.001 | .130 (E) | 104 | 0 | < .001 | < .001 |
| Benfluralin | .002 | 277 | 1 | 0.7 | <.002 | .030 | 104 | 0 | < .002 | < .002 |
| Butylate | .002 | 277 | 2 | 0.7 | <.002 | .018 | 104 | 0 | < .002 | < .002 |
| Carbaryl | .003 | 279 | 23 | 28.3a | .064 | 2.00 (E) | 105 | 0 | < .003 | < .003 |
| Carbofuran | .003 | 279 | 7 | 5.7a | <.003 | .460 (E) | 105 | 0 | < .003 | < .003 |
| Chlorpyrifos | .004 | 277b | 12 | 17.0a | .008 | .041 | 104 | 0 | < .004 | < .004 |
| Cyanazine | .004 | 279b | 17 | 23.3a | .078 | 3.00 | 105 | 0 | < .004 | < .004 |
| DCPA | .002 | 277c | 9 | 12.6a | .002 | .045 | 104c | 1a | < .002 | .001 (E) |
| DCPA | .002 | 277c | 9 | 12.6a | .002 | .045 | 104c | 1a | < .002 | .001 (E) |
| p,p'-DDE | .006 | 277c | 6 | 2.2a | <.006 | .023 | 104c | 10a | < .006 | .001 (E) |
| Desethylatrazine | .002 | 279b | 80 | 79.6a | .150 | .690 (E) | 105b | 38a | .140 | 1.40 (E) |
| Diazinon | .002 | 277 | 21 | 30.0a | .071 | 1.40 | 104 | 0 | <.002 | <.002 |
| Dieldrin | .001 | 277 | 2 | 0.7 | <.001 | .018 | 104 | 0 | <.001 | <.001 |
| 2,6-Diethylanaline | .003 | 277b | 1 | 0.4a | <.003 | .014 (E) | 104 | 0 | <.003 | <.003 |
| EPTC | .002 | 277 | 5 | 3.6a | <.002 | .012 | 104 | 3a | <.002 | .013 |
| Ethoprop | .003 | 279 | 1 | 0.4 | <.003 | .027 | 105 | 0 | <.003 | <.003 |
| Fonofos | .003 | 277 | 3 | 2.2a | <.003 | .084 | 104 | 0 | <.003 | <.003 |
| gamma-HCH | .004 | 277 | 2 | 1.1 | <.004 | .025 | 104 | 0 | <.004 | <.004 |
| Linuron | .002 | 277 | 5 | 10.5 | .009 | 1.40 | 104 | 0 | <.002 | <.002 |
| Malathion | .005 | 277 | 5 | 5.1a | <.005 | .410 | 104 | 0 | <.005 | <.005 |
| Methylparathion | .006 | 277 | 4 | 3.6a | <.006 | .080 | 104 | 0 | <.006 | <.006 |
| Metolachlor | .002 | 279b | 83 | 84.9a | .990 | 23.0 (E) | 105 | 20a | .009 | .460 |
| Metribuzin | .004 | 277 | 9 | 11.6a | .008 | .160 | 104 | 2a | <.004 | .012 |
| Napropamide | .003 | 279 | 2 | 0.7 | <.003 | .024 | 105 | 0 | <.003 | <.003 |
| Pebulate | .004 | 277 | 0 | 0.0 | <.004 | <.004 | 104 | 1a | <.004 | .004 (E) |
| Pendimethalin | .004 | 277 | 5 | 13.4a | .022 | .320 | 104 | 0 | <.004 | <.004 |
| Prometon | .018 | 279c | 68 | 71.7a | .077 | 1.70 (E) | 105 c | 16 a | .018 | .900 (E) |
| Propachlor | .007 | 279b | 1 | 1.4a | <.007 | .046 | 105 | 0 | <.007 | <.007 |
| Simazine | .005 | 279b | 83 | 84.9a | .510 | 4.40 | 105 | 23a | .065 | .210 |
| Tebuthiuron | .010 | 279c | 22 | 21.5a | .010 | .220 | 105 | 2a | <.010 | .086 |
| Terbucil | .007 | 274b | 7 | 6.9a | <.007 | .130 (E) | 104c | 1a | <.007 | .260 (E) |
| Trifluralin | .002 | 277 | 9 | 4.7 | <.002 | .027 | 104 | 0 | <.002 | <.002 |
| Samples analyzed by high-performance liquid chromatography with detection by ultraviolet spectroscopy (Werner and others, 1996) (8 surface-water sites sampled for this analysis method) | ||||||||||
| Chlorothalonil | .035 | 126 | 1 | 0.8a | <.035 | .100 | 82 | 0 | <.035 | <.035 |
| 2,4-D | .035 | 127 | 4 | 19.7a | .340 | 2.80 | 82 | 0 | <.035 | <.035 |
| Dicamba | .035 | 127 | 0 | 0.0 | <.035 | <.100 | 82 | 1 | <.035 | .070 |
| Dichlobenil | .020 | 128 | 0 | 0.0 | <.020 | <.100 | 82 | 1a | <.020 | .100 (E) |
| Dichlorprop | .032 | 127 | 1 | 0.8 | <.032 | .150 | 82 | 0 | <.032 | <.032 |
| Diuron | .020 | 128b | 2 | 14.8a | .090 | .690 (E) | 82 | 0 | <.020 | <.040 |
| MCPA | .050 | 127 | 1 | 1.6 | <.050 | 1.30 | 82 | 0 | <.050 | <.050 |
| Oryzalin | .019 | 128 | 1 | 6.3a | <.019 | 1.90 | 82 | 0 | <.090 | <.038 |
| Propoxur | .035 | 118 | 0 | 0.0 | <.035 | <.035 | 77 | 1 | <.035 | .060 |
| Triclopyr | .050 | 127 | 2 | 3.9a | <.050 | .830 | 82 | 0 | <.050 | <.050 |
| aSome detections of estimated values were reported for
this pesticide. bLess than 50 percent of detectable concentrations were estimated below the MDL or MRL. c50 percent or more of detectable concentrations were estimated below the MDL or MRL. | ||||||||||